Porosity is the ratio of the pore volume to the bulk volume of a substance.
Primary porosity: the main or original porosity system in a rock or unconfined alluvial deposit.
Secondary porosity: A subsequent or separate porosity system in a rock, often enhancing the overall porosity of a rock. This can be a result of the chemical leaching of minerals or the generation of a fracture system. This can replace the primary porosity or coexist with it.
Effective porosity (also called open porosity): Refers to the fraction of the total volume in which fluid flow is effectively taking place and includes catenary and dead-end (as these pores cannot be flushed, but they can cause fluid movement by release of pressure like gas expansion[3]) pores and excludes closed pores (or non-connected cavities). This is very important for groundwater and petroleum flow, as well as for solute transport.
Ineffective porosity (also called closed porosity): Refers to the fraction of the total volume in which fluids or gases are present but in which fluid flow can not effectively take place and includes the closed pores. Understanding the morphology of the porosity is thus very important for groundwater and petroleum flow
Dual porosity: Refers to the conceptual idea that there are two overlapping reservoirs that interact. In fractured rock aquifers, the rock mass and fractures are often simulated as being two overlapping but distinct bodies. Delayed yield and leaky aquifer flow solutions are both mathematically similar solutions to that obtained for dual porosity; in all three cases, water comes from two mathematically different reservoirs (whether or not they are physically different)..
Φ = Vp / Vb = ( Vb - Vm )/ Vb
Where:
Vp: pore space volume
Vm: matrix (solid rock) volume
Vb: bulk volume (Vp + Vm)
Bulk volume (Vb): can be determined directly from core dimensions if we have a fluid-saturated regularly shaped core (normally cylindrical), or by fluid displacement methods by weight where the density of the solid matrix and the displacing fluid is known, or directly by volume displacement.
Matrix volume (Vm): can be calculated from the mass of a dry sample divided by the matrix density. It is also possible to crush the dry solid and measure its volume by displacement, but this will give total porosity rather than effective (interconnected) porosity
Pore space volume (Vp): can also be determined using gas expansion methods.